1,306 research outputs found

    Electron energy-loss spectrometry on lithiated graphite

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    Transmission electron energy-loss spectrometry was used to investigate the electronic states of metallic Li and LiC6, which is the Li-intercalated graphite used in Li-ion batteries. The Li K edges of metallic Li and LiC6 were nearly identical, and the C K edges were only weakly affected by the presence of Li. These results suggest only a small charge transfer from Li to C in LiC6, contrary to prior results from surface spectra obtained by x-ray photoelectron spectroscopy. Effects of radiation damage and sample oxidation in the transmission electron microscopy are also reported

    Electrochemical Evaluation of LaNi_(5–x)Ge_x Metal Hydride Alloys

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    We report a detailed evaluation of Ge-substituted LaNi_5 for electrochemical application as a negative electrode in alkaline rechargeable cells. Alloys with small substitutions of Ge for Ni show operating pressures, chargeability, cyclic lifetime, and kinetics for hydrogen absorption and desorption all superior to those found in many other substituted LaNi_5 alloys. These improved properties were achieved with a minimal reduction in hydrogen storage capacity

    Electrochemical Studies on LaNi5–xSnx Metal Hydride Alloys

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    Electrochemical studies were performed on LaNi5–xSnx with 0 <= x <= 0.5. We measured the effect of the Sn substituent on the kinetics of charge-transfer and diffusion during hydrogen absorption and desorption, and the cyclic lifetimes of LaNi5–-xSnx electrodes in 250 mAh laboratory test cells. We report beneficial effects of making small substitutions of Sn for Ni in LaNi5 on the performance of the metal hydride alloy anode in terms of cyclic lifetime, capacity, and kinetics. The optimal concentration of Sn in LaNi5–xSnx alloys for negative electrodes in alkaline rechargeable secondary cells was found to lie in the range 0.25 <= x <= 0.3

    Electrochemical Properties of LaNi5–xGex Alloys in Ni-MH Batteries

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    Electrochemical studies were performed on LaNi5–xGex metal hydride alloys with 0 <= x <= 0.5. We carried out single-electrode studies to understand the effects of the Ge substituent on the hydrogen absorption characteristics, the electrochemical capacity, and the electrochemical kinetics of hydrogen absorption and desorption. The electrochemical characteristics of the Ge-substituted alloys are compared to those of the Sn-substituted alloys reported earlier. LaNi5–xGex alloys show compositional trends similar to LaNi5–xSnx alloys, but unlike the Sn-substituted alloys, Ge-substituted alloys continue to exhibit facile kinetics for hydrogen absorption/desorption at high solute concentrations. Cycle lives of LaNi5–xGex electrodes were measured in 300 mAh laboratory test cells and were found to be superior to the Sn-substituted LaNi5 and comparable to a Mm(Ni,Co,Mn,Al)5 alloy. The optimum Ge content for LaNi5–xGex metal hydride alloys in alkaline rechargeable cells is in the range 0.4 <= x <= 0.5

    42. Male and Female Differences Regarding Buffers to STEM Fields

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    STEM (Science, Technology, Engineering, and Mathematics) fields are dominated by males, with societal norms discouraging many women from pursuing a career in STEM. Women in the STEM fields benefit from buffers that mediate the negative effects of discrimination. In our pilot study, we found that playing video games with a romantic partner served as a buffer for female gamers, facilitating their continued play. Understanding male attitudes towards female gamers helps to identify additional buffers and potential ramifications. Our current project empirically explored the male opinion of female gamers and its effect on women’s decision to enter into the STEM fields. We hypothesized that male participants would rate women as less accomplished players, refer to them as weak, and expect women to lack competitiveness. These negative expectations have the potential to influence women’s decisions to pursue STEM careers, specifically game design and programming. Data were collected using an online survey taken by 204 undergraduate males, 300 Caucasian women and 300 minority women. We assessed the participants’ reactions to discrimination and harassment, likelihood to enter a STEM field, and opinions of female gamers. We found that male gamers displayed discriminatory, sexist beliefs towards female gamers which contribute to similar perceptions about the prevalence of harassment in online gaming. Our results explore the link between these beliefs and the likelihood of female gamers pursuing STEM careers. Our study raises awareness of the lack of female presence in STEM fields and explains this deficiency by discerning the male perspective while examining potential buffers. Keywords: Video games, gamers, STEM, discrimination, prejudice, programming, buffers, barriers, sexis

    inTrack: High Precision Tracking of Mobile Sensor Nodes

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    Radio-interferometric ranging is a novel technique that allows for fine-grained node localization in networks of inexpensive COTS nodes. In this paper, we show that the approach can also be applied to precision tracking of mobile sensor nodes. We introduce inTrack, a cooperative tracking system based on radio-interferometry that features high accuracy, long range and low-power operation. The system utilizes a set of nodes placed at known locations to track a mobile sensor. We analyze how target speed and measurement errors affect the accuracy of the computed locations. To demonstrate the feasibility of our approach, we describe our prototype implementation using Berkeley motes. We evaluate the system using data from both simulations and field tests

    Ball bearing vibrations amplitude modeling and test comparisons

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    Bearings generate disturbances that, when combined with structural gains of a momentum wheel, contribute to induced vibration in the wheel. The frequencies generated by a ball bearing are defined by the bearing's geometry and defects. The amplitudes at these frequencies are dependent upon the actual geometry variations from perfection; therefore, a geometrically perfect bearing will produce no amplitudes at the kinematic frequencies that the design generates. Because perfect geometry can only be approached, emitted vibrations do occur. The most significant vibration is at the spin frequency and can be balanced out in the build process. Other frequencies' amplitudes, however, cannot be balanced out. Momentum wheels are usually the single largest source of vibrations in a spacecraft and can contribute to pointing inaccuracies if emitted vibrations ring the structure or are in the high-gain bandwidth of a sensitive pointing control loop. It is therefore important to be able to provide an a priori knowledge of possible amplitudes that are singular in source or are a result of interacting defects that do not reveal themselves in normal frequency prediction equations. This paper will describe the computer model that provides for the incorporation of bearing geometry errors and then develops an estimation of actual amplitudes and frequencies. Test results were correlated with the model. A momentum wheel was producing an unacceptable 74 Hz amplitude. The model was used to simulate geometry errors and proved successful in identifying a cause that was verified when the parts were inspected
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